New Insights into the Anion Transport Selectivity and Mechanism of Tren-based Tris-(thio)ureas

Jowett, Laura A.; Howe, Ethan N.W.; Wu, Xin; Busschaert, Nathalie; Gale, Philip A.

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Open Access

Field	Value	Language
dc.contributor.author	Jowett, Laura A.
dc.contributor.author	Howe, Ethan N.W.
dc.contributor.author	Wu, Xin
dc.contributor.author	Busschaert, Nathalie
dc.contributor.author	Gale, Philip A.
dc.date.accessioned	2019-08-26
dc.date.available	2019-08-26
dc.date.issued	2018-06-19
dc.identifier.citation	Jowett, L. A., Howe, E. N. W., Wu, X., Busschaert, N., & Gale, P. A. (2018). New Insights into the Anion Transport Selectivity and Mechanism of Tren-based Tris-(thio)ureas. Chemistry - A European Journal, 24(41), 10475–10487. https://doi.org/10.1002/chem.201801463	en
dc.identifier.uri	http://hdl.handle.net/2123/20954
dc.description.abstract	The anion transport properties of a series of previously reported tren-based anionophores have been revisited using new assays designed to measure anion uniport. This study provides new insights into the transport mechanism and selectivity of this important class of transporters. Specifically, we report the chloride and nitrate transport selectivity of these systems and quantify sulfate transport to determine EC50 values for sulfate transport for the first time. Two new assays were developed to study bicarbonate transport allowing accurate quantification of chloride/bicarbonate exchange.	en
dc.description.sponsorship	ARC	en
dc.language.iso	en	en
dc.publisher	Wiley VCH	en
dc.relation	ARC DP180100612 ARC DP170100118 ARC LE180100050	en
dc.rights	Other	en
dc.subject	supramolecular chemistry	en
dc.subject	anion transport	en
dc.title	New Insights into the Anion Transport Selectivity and Mechanism of Tren-based Tris-(thio)ureas	en
dc.type	Article	en
dc.subject.asrc	030302	en
dc.identifier.doi	10.1002/chem.201801463
dc.type.pubtype	Pre-print	en
usyd.faculty	Faculty of Science, School of Chemistry