Investigating the Influence of Steric Hindrance on Selective Anion Transport
| Field | Value | Language |
| dc.contributor.author | Jowett, Laura A. | |
| dc.contributor.author | Ricci, Angela | |
| dc.contributor.author | Wu, Xin | |
| dc.contributor.author | Howe, Ethan N.W. | |
| dc.contributor.author | Gale, Philip A. | |
| dc.date.accessioned | 2019-04-03 | |
| dc.date.available | 2019-04-03 | |
| dc.date.issued | 2019-04-02 | |
| dc.identifier.citation | Jowett, L.A.; Ricci, A.; Wu, X.; Howe, E.N.W.; Gale, P.A. Investigating the Influence of Steric Hindrance on Selective Anion Transport. Molecules 2019, 24, 1278. https://doi.org/10.3390/molecules24071278 | en |
| dc.identifier.uri | http://hdl.handle.net/2123/20241 | |
| dc.description.abstract | A series of symmetrical and unsymmetrical alkyl tren based tris-thiourea anion transporters were synthesised and their anion binding and transport properties studied. Overall, increasing the steric bulk of the substituents resulted in improved chloride binding and transport abilities. Including a macrocycle in the scaffold enhanced the selectivity of chloride transport in the presence of fatty acids, by reducing the undesired H+ flux facilitated by fatty acid flip-flop. This study demonstrates the benefit of including | en |
| dc.description.sponsorship | ARC and EPSRC | en |
| dc.language.iso | en | en |
| dc.publisher | MDPI | en |
| dc.relation | ARC DP180100612 | en |
| dc.rights | Other | en |
| dc.subject | anion transport | en |
| dc.subject | thiourea | en |
| dc.subject | lipid bilayer | en |
| dc.title | Investigating the Influence of Steric Hindrance on Selective Anion Transport | en |
| dc.type | Article | en |
| dc.subject.asrc | 030302 | en |
| dc.identifier.doi | doi:10.3390/molecules24071278 | |
| dc.type.pubtype | Publisher's version | en |
| usyd.faculty | Faculty of Science, School of Chemistry |
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