A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity

Spooner, Michael J.; Gale, Philip A.

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Open Access

Field	Value	Language
dc.contributor.author	Spooner, Michael J.
dc.contributor.author	Gale, Philip A.
dc.date.accessioned	2019-02-07
dc.date.available	2019-02-07
dc.date.issued	2018-01-01
dc.identifier.citation	Spooner, Michael J. and Gale, Philip A. (2018) A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*. Supramolecular Chemistry, 1-6. (doi:10.1080/10610278.2018.1431394).	en
dc.identifier.uri	http://hdl.handle.net/2123/19958
dc.description.abstract	We report the synthesis of a tripodal tris-selenourea transporter scaffold. The Cl− and NO− 3 transport activity of the compound has been compared extensively with the analogous oxo- and thiourea compounds. We found that the selenourea demonstrates remarkably similar transport efficacy and mechanistic properties to the equivalent thiourea, but demonstrates flipped selectivity for Cl− over NO−3.	en
dc.description.sponsorship	EPSRC, ARC	en
dc.language.iso	en	en
dc.publisher	Taylor & Francis	en
dc.relation	ARC DP170100118	en
dc.rights	Other	en
dc.subject	supramolecular chemistry	en
dc.title	A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity	en
dc.type	Article	en
dc.subject.asrc	030302	en
dc.identifier.doi	10.1080/10610278.2018.1431394
dc.type.pubtype	Author accepted manuscript	en
dc.rights.other	This is an Accepted Manuscript of an article published by Taylor & Francis in Supramolecular Chemistry on, 08 Feb 2018, available online: https://www.tandfonline.com/doi/full/10.1080/10610278.2018.1431394	en
usyd.faculty	Faculty of Science, School of Chemistry