|Title:||A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity|
|Authors:||Spooner, Michael J.|
Gale, Philip A.
|Publisher:||Taylor & Francis|
|Citation:||Spooner, Michael J. and Gale, Philip A. (2018) A tripodal tris-selenourea anion transporter matches the activity of its thio- analogue but shows distinct selectivity*. Supramolecular Chemistry, 1-6. (doi:10.1080/10610278.2018.1431394).|
|Abstract:||We report the synthesis of a tripodal tris-selenourea transporter scaffold. The Cl− and NO− 3 transport activity of the compound has been compared extensively with the analogous oxo- and thiourea compounds. We found that the selenourea demonstrates remarkably similar transport efficacy and mechanistic properties to the equivalent thiourea, but demonstrates flipped selectivity for Cl− over NO−3.|
|Rights and Permissions:||This is an Accepted Manuscript of an article published by Taylor & Francis in Supramolecular Chemistry on, 08 Feb 2018, available online: https://www.tandfonline.com/doi/full/10.1080/10610278.2018.1431394|
|Type of Work:||Article|
|Type of Publication:||Post-print|
|Appears in Collections:||Research Papers and Publications. Chemistry|
|Se Paper Manuscript FINAL.pdf||787.79 kB||Adobe PDF|
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