Synthesis, structures and properties of transition metal doped SrIrO3

Field	Value	Language
dc.contributor.author	Ilyas, Qasim	en_US
dc.contributor.author	Brendan, J Kennedy
dc.contributor.author	Avdeev, Maxim
dc.date.accessioned	2021-03-22T00:17:09Z
dc.date.available	2021-03-22T00:17:09Z
dc.date.issued	2013
dc.identifier.uri	https://hdl.handle.net/2123/24691
dc.description.abstract	The synthesis of some transition metal SrIr1_xMxO3 type oxides is described. These have an orthorhombic perovskite type-structure and are only found when the formal oxidation state of the Ir is approximately equal to +4.5 and for M = Fe, Co, Ni and Zn. Occupancy of the TM eg type orbitals appears to contribute to the break-down of the dimeric motif seen in the 6H-SrIrO3 structure. Variable temperature resistivity measurements show that SrIr0.8Zn0.2O3 is a metal; SrIr0.8Ni0.2O3 an non-metal and SrIr0.8Co0.2O3 undergoes a temperature dependent metal-insulator transition.	en_US
dc.language.iso	en	en_US
dc.title	Synthesis, structures and properties of transition metal doped SrIrO3	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1039/C3TA00540B

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