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dc.contributor.authorReynolds, Emily
dc.contributor.authorZhang, Zhaoming
dc.contributor.authorAvdeev, Maxim
dc.contributor.authorThorogod, Gordon J
dc.contributor.authorPoineau, Frederic
dc.contributor.authorCzerwinski, Kenneth R
dc.contributor.authorKimpton, Justin A
dc.contributor.authorKennedy, Brendan J
dc.date.accessioned2019-02-21
dc.date.available2019-02-21
dc.date.issued2017-01-01
dc.identifier.citationInorganic Chemistry 2017, 56, 9219-9224. DOI: 10.1021/acs.inorgchem.7b01235en_AU
dc.identifier.urihttp://hdl.handle.net/2123/20038
dc.description.abstractThe structure of TcO2 between 25 and 1000 °C has been determined in-situ using powder diffraction methods and is found to remain monoclinic in space group P21/c. The thermal expansion in TcO2 is highly anisotropic with negative thermal ex-pansion of the b-axis observed above 700 °C. This is the result of an anomalous expansion along the a-axis that is a consequence of weakening of the Tc-Tc bonds.en_AU
dc.description.sponsorshipAustralian Synchrotron Australian Research Councilen_AU
dc.publisherACSen_AU
dc.relationARCen_AU
dc.rightsCopyright © 2017 American Chemical Societyen_AU
dc.subjectTechnetiumen_AU
dc.titleThermal Expansion Behavior in TcO2. Towards breaking the Tc-Tc bond.en_AU
dc.typeArticleen_AU
dc.subject.asrcFoR::030206 - Solid State Chemistryen_AU
dc.identifier.doi10.1021/acs.inorgchem.7b01235
dc.type.pubtypePre-printen_AU


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