Thermal Expansion Behavior in TcO2.  Towards breaking the Tc-Tc bond.

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Field	Value	Language
dc.contributor.author	Reynolds, Emily
dc.contributor.author	Zhang, Zhaoming
dc.contributor.author	Avdeev, Maxim
dc.contributor.author	Thorogod, Gordon J
dc.contributor.author	Poineau, Frederic
dc.contributor.author	Czerwinski, Kenneth R
dc.contributor.author	Kimpton, Justin A
dc.contributor.author	Kennedy, Brendan J
dc.date.accessioned	2019-02-21
dc.date.available	2019-02-21
dc.date.issued	2017-01-01
dc.identifier.citation	Inorganic Chemistry 2017, 56, 9219-9224. DOI: 10.1021/acs.inorgchem.7b01235	en
dc.identifier.uri	http://hdl.handle.net/2123/20038
dc.description.abstract	The structure of TcO2 between 25 and 1000 °C has been determined in-situ using powder diffraction methods and is found to remain monoclinic in space group P21/c. The thermal expansion in TcO2 is highly anisotropic with negative thermal ex-pansion of the b-axis observed above 700 °C. This is the result of an anomalous expansion along the a-axis that is a consequence of weakening of the Tc-Tc bonds.	en
dc.description.sponsorship	Australian Synchrotron Australian Research Council	en
dc.publisher	ACS	en
dc.relation	ARC	en
dc.rights	Other	en
dc.subject	Technetium	en
dc.title	Thermal Expansion Behavior in TcO2. Towards breaking the Tc-Tc bond.	en
dc.type	Article	en
dc.subject.asrc	FoR::030206 - Solid State Chemistry	en
dc.identifier.doi	10.1021/acs.inorgchem.7b01235
dc.type.pubtype	Preprint	en
usyd.faculty	Faculty of Science, School of Chemistry