Browsing School of Chemistry by subject "0306 Physical Chemistry (incl. Structural)"
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Depletion of the Lubricant from Lubricant-Infused Surfaces due to an Air/Water Interface
Published 8 March 20Lubricant-infused surfaces (LIS) have emerged as an innovative way to combat several modern challenges such as biofouling, ice formation, and surface drag. The favorable properties of LIS are dependent on the presence and ...Open AccessArticle -
E_File_10 - Free-Base Porphyrin 'Distal' Structure Potential Energy Surface Explorer.cdf
Published 2022-11-02Mathematica computable document format as described in Chapter 6 and Appendix F. Can be executed in Mathematica or using the free Wolfram PlayerOpen AccessInteractiveResource -
E_File_12 - SmBn partitioned Polytope Formalism of constitutional isomerism graphing.nb
Published 2022-11-02Mathematica script for interactively graphing Dmh site symmetric 𝒮𝑚ℬ𝑛 partitioning approach to the Polytope Formalism of constitutional isomerism. This script uses the .dat output files from the Fortran software in ...Open AccessSoftware -
E_File_13 - S4B2_genera{1-28}_all.zip
Published 2022-11-04Zip archive folder of the D4h site symmetric 𝒮4ℬ2 partitioned, full 1st order and 2nd-order motions graph output from the Mathematica1 graphing software in E_File_12.Open AccessOther -
E_File_14 - Ch6 DFT optimised coordinates.pdf
Published 2022-11-02Density-Functional Theory optimised coordinates for molecules from Thesis Chapter 6. Calculation details for all species are given along with systematic chemical names for most.Open AccessDataset -
E_File_2 four transoid B2OF2pqx isomers.zip
Published 2018Archive file containing three different formats of the same animation. Animation of the four transoid B2OF2pqx stereoisomers rotating in space to illustrate the structural differences. See Thesis chapter 4 for details.Open AccessAudiovisual -
E_File_3 - four cisoid B2OF2pqx isomers.zip
Published 2018Archive file containing three different formats of the same animation. Animation of the four conceptual cisoid B2OF2pqx stereoisomers rotating in space to illustrate the structural differences. See Thesis chapter 4 for details.Open AccessAudiovisual -
E_File_4 diastereomeric akamptisomerisation.zip
Published 2018Archive file containing three different formats of the same animation. Animation of the akamptisomerisation reaction interconverting two diastereomeric transoid B2OF2pqx stereoisomers. See Thesis chapter 4 for details.Open AccessAudiovisual -
E_File_6 - hula-twist-like akamptisomeriation.zip
Published 2022-11-02Archive file containing three different formats of the same animation. Animation of the hula-twist-like mechanism affecting the akamptisomerisation reaction between two transoid B2OF2pqx stereoisomers. See Thesis chapter ...Open AccessAudiovisual -
E_File_7 - strepsisomerisation.zip
Published 2022-11-02Archive file containing three different formats of the same animation. Animation of strepsisomerisation mechanisms affecting the stereoisomerisation of all four transoid B2OF2pqx stereoisomers. See Thesis chapter 4 for details.Open AccessAudiovisual -
E_File_9 - CAS SciFinder search results March 2019.zip
Published 2022-11-02Zip archive folder containing 32 .pdf files listing the March 2019 Chemical Abstracts Service SciFinder search results as described in Thesis Chapter 5.Open AccessDataset -
Emission Decay Pathways Sensitive to Circular Polarization of Excitation
Published 2018The photophysical properties of conjugated materials can be strongly affected by the nature of intermolecular interactions. Toward this aim, supramolecular self-assembly facilitates efficient packing of molecules into ...Open AccessArticle -
Enhancing Spontaneous Droplet Motion on Structured Surfaces with Tailored Wedge Design
Published 2020Spontaneous liquid transport has a wide variety of applications, including fog harvesting, microfluidics, and water-oil separation. Understanding of the droplet movement dynamics on structured surfaces is essential ...Open AccessArticle -
Evaluating medical device and material thrombosis under flow: current and emerging technologies
Published 2020Although blood-contacting medical devices are used widely, blood clot formation (thrombosis) leads to device failure and potentially catastrophic adverse thrombotic events for patients, such as stroke or pulomonary embolism. ...Open AccessArticle -
How Slippery are SLIPS? Measuring Effective Slip on Lubricated Surfaces with Colloidal Probe Atmoc Force Microscopy
Published 2019Lubricant-infused surfaces have attracted great attention recently and are described as slippery (SLIPS). Here we measured hydrodynamic drainage forces on SLIPS by colloid probe atomic force microscopy (AFM) and quantified ...Open AccessArticle -
Large Effective Slip on Lubricated Surfaces Measured with Colloidal Probe AFM
Published 2020In this work, we study the interfacial boundary conditions at the interface between two immiscible liquids under laminar flow. We measure the hydrodynamic drainage forces acting on a colloid probe as it approaches a flat ...Open AccessArticle -
Life and death of liquid-infused surfaces: a review on the choice, analysis and fate of the infused liquid layer
Published 2020Liquid-infused surfaces (or lubricant-infused surfaces) (LIS) are a new class of functional materials introduced in 2011. Their exceptional properties have earned them a place at the forefront of many fields including ...Open AccessArticle -
Marine Antifouling Behavior of Lubricant-Infused Nanowrinkled Polymeric Surfaces
Published 2018A new family of polymeric, lubricant-infused, nanostructured wrinkled surfaces was designed that effectively retains inert non-toxic silicone oil, upon draining by spin-coating and vigorous shear for two weeks. The wrinkled ...Open AccessArticle -
Premature detonation of an ammonium nitrate emulsion in reactive ground
Published 2015When ammonium nitrate emulsions are used in blast holes containing pyrite, they can exothermally react with pyrite, causing the emulsion to intensively heat and detonate prematurely. Such premature detonations can inflict ...Open AccessArticle -
Receding Contact Line Motion on Nanopatterned and Micropatterned Polymer Surfaces
Published 2017Surface properties such as topography and chemistry affect the motion of the three-phase contact line (solid/liquid/air), which in turn affects the contact angle of a liquid moving on a solid surface. In this work, the ...Open AccessArticle