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dc.contributor.authorMurase, Ryuichi
dc.date.accessioned2019-05-24
dc.date.available2019-05-24
dc.date.issued2019-02-28
dc.identifier.urihttp://hdl.handle.net/2123/20446
dc.description.abstractThis thesis details the study of structure-property relationships in redox-active coordination frameworks. The structural tuneability of framework materials was used to create a series of inter-related, hierarchical frameworks. A combined spectroscopic, electrochemical, electronic and structural study was used to derive key parameters of redox-active frameworks towards the assessment of their degree of delocalisation – a key feature for their integration into application such as Field-Effect Transistor (FET) devices, energy storage, optoelectronics and many more. Despite the wealth of applied studies on redox-active frameworks, fundamental understandings of electron transfer within a framework manifold and the consequence of redox-modulation within a crystalline 3-D material is less understood. The work herein describes a novel ‘hierarchical approach’ to elucidating the fundamental relationships that exist between the structural, electrochemical, spectroscopic and electronic properties applicable beyond electroactive frameworks. A perspective of previously reported redox-active frameworks is presented in Chapter 1. Chapters 2-5 explores two approaches, the ‘through-bond’ and ‘through-space’ approach, to induce long-ranged electronic delocalisation in coordination framework materials. A number of key physical properties such as redox state, conductivity and extent of delocalisation of these examples were characterised to build and recognise structure-property relationships. Understanding the nature of electron transfer in a framework manifold should pave the way towards designing materials with fine-tuned propertiesen_AU
dc.publisherUniversity of Sydneyen_AU
dc.publisherFaculty of Scienceen_AU
dc.publisherSchool of Chemistryen_AU
dc.rightsThe author retains copyright of this thesis. It may only be used for the purposes of research and study. It must not be used for any other purposes and may not be transmitted or shared with others without prior permission.en_AU
dc.subjectredox-activeen_AU
dc.subjectmetal-organic frameworken_AU
dc.subjectMOFen_AU
dc.subjectcoordination polymeren_AU
dc.subjectconductiveen_AU
dc.subjectmixed-valenceen_AU
dc.subject.otherincludes published articlesen_AU
dc.titleElucidating the Structure-Property Relationships of Hierarchically Designed Redox-Active Frameworksen_AU
dc.typePhD Doctorateen_AU
dc.type.pubtypeDoctor of Philosophy Ph.D.en_AU
dc.description.disclaimerAccess is restricted to staff and students of the University of Sydney . UniKey credentials are required. Non university access may be obtained by visiting the University of Sydney Library.en_AU


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